Valentin married Katharina Ochs on 15 Apr 1861 in Trippstadt, Pfalz, Bayern. Katharina was born in in Linden, Pfalz, Bayern. [Group Sheet] [Family Chart]

Valentin married Anna Ritter on 10 Jul 1889 in Hauenstein, Pfalz, Bayern. Anna (daughter of Joseph Ritter and Cäcilia Seibel) was born on 29 Mar 1871 in Hauenstein, Pfalz, Bayern; was christened on 13 Apr 1871 in Hauenstein, Pfalz, Bayern; died on 31 Dec 1894 in Hauenstein, Pfalz, Bayern. [Group Sheet] [Family Chart]

Valentin married Magdalena Amanda Elisabetha Heiligenthal [Group Sheet] [Family Chart]