Georg married Anna Maria Kettenring on 10 Nov 1778 in Pirmasens, Pfalz, Bayern. Anna (daughter of Johannes Adam Kettenring and Anna Ottilia Anstett) was born on 12 Sep 1762 in Salzwoog, Pfalz. [Group Sheet] [Family Chart]

1. Johannes Heinrich Knopf was born on 10 Nov 1785 in Pirmasens, Pfalz.
2. Anna Maria Knopf was born on 11 Sep 1788; was christened on 11 Sep 1788 in Lemberg bei Pirmasens, Pfalz, Bayern.
3. Anna Ottillia Knopf was born on 13 Sep 1791 in Lemberg bei Pirmasens, Pfalz; died on 19 Jul 1797 in Lemberg bei Pirmasens, Pfalz.
4. Georg Daniel Knopf was born on 16 Jul 1798 in Lemberg bei Pirmasens, Pfalz.
5. Johannes Adam Knopf was born on 25 Jan 1801 in Lemberg bei Pirmasens, Pfalz; was christened on 29 Jan 1801 in Lemberg bei Pirmasens, Pfalz; died on 8 Jun 1881 in Monroe County, Ohio, USA; was buried in Evangelical Reformed Church Cemetery, Lewisville, Monroe County, Ohio, USA.